The post you are replying to is nearly 2 years old, so I am unsure that the poster will see your question, hence my intervention.
What you are asking is difficult for many reasons.
1] I've never used PC Mover and I cannot attest to its usefulness. But in general Windows broke this, "copy program files to another computer and they will work", many many years ago. I believe the last Windows version it was possible with any guarantee of success was from Windows 95 to Windows 95. So although I see where PC Mover is said to be great, I am not convinced.
The problem is varied. If some program or other installs its files in just one location/folder then there is a chance that moving the folder to a new computer might work. But since Windows 98, program installations have installed files in many different locations on a computer system, as well as created registry entries and system files, and so on and such. Trying to track those down to copy them across is a huge task, and is rarely successful.
That's why the only real solution is to "reinstall" programs onto another OS.
2] XP mode is said to be very good for installing and running those programs that cannot be installed into Windows 7. But there is really only one answer here. Try it and see. No-one can tell you it will always work.
3] Windows 7 no longer has DOS, but you might be able to use something like DOSBox to emulate DOS on Win 7.
4] Your own created Office files, eg Word and Excel will not be able to be used on Windows 7 without Microsoft Office installed, (or you can use the free, open source office apps like OpenOffice or LibreOffice).
You can copy those word.doc files and Excel spreadsheet files across to Windows 7, but you will still need an application to read and edit them.
I have the same problem on my Win 7. It doesn't have Office. So although I have my Word files and Excel files copied to this system, I cannot open them to edit them I can, however, view them with Microsoft's Word Viewer and Excel viewer, both free.
5] Printers are a problem. If HP does not have a suitable Windows 7 driver for your Laserjet then there is little you can do. Attempting to set up a printer thru' Windows 7 into XP mode is, I understand, very difficult.
Sorry this reply is so full of uncertainties.
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